Organic photovoltaics: A journey through time, advancements, and future opportunities

  • Gennadiy Bulavko Taras Shevchenko National University of Kyiv
Keywords: renewable energy, solar cell efficiency, material science, sustainable technology, energy conversion, environmental impact

Abstract

This comprehensive study explores the realm of organic photovoltaics, a pivotal green energy technology, tracing its journey from early theoretical concepts to its current status as a promising avenue for sustainable energy production. The research meticulously examines the series of developmental milestones in the conversion of solar energy into electrical power, with a specialized focus on the evolution, technological advancements, and the inherent challenges faced by organic solar cells. Delving into the foundational aspects of organic photovoltaics, this paper reviews the initial discovery and subsequent enhancements in material science that have significantly influenced the efficiency and practicality of organic solar cells. It provides a detailed analysis of the various organic materials used over the years, including small molecules and polymers, discussing their light-absorbing capabilities, charge transport properties, and the innovative engineering behind the architectures of organic photovoltaic devices. A substantial portion of the study is dedicated to highlighting the unique advantages of organic photovoltaics, such as their lightweight nature, flexibility, and potential for low-cost production through roll-to-roll processes. These benefits are juxtaposed with the current limitations of organic photovoltaic technology, including comparatively lower efficiency and lifespan issues, to present a balanced perspective on the current state of organic photovoltaic development. Furthermore, the paper explores the environmental impact of organic solar cells, emphasizing their role in reducing carbon footprint and dependency on fossil fuels. It assesses the lifecycle analyses of organic photovoltaics, from manufacturing to disposal, to underscore their potential as an eco-friendly alternative to traditional photovoltaic technologies. In addressing the future prospects of organic photovoltaics, the research outlines the ongoing efforts in material innovation, device engineering, and scalability challenges. It discusses the role of interdisciplinary collaboration in overcoming the technical hurdles and enhancing the commercial viability of organic photovoltaics. The potential for integration of organic photovoltaics s into the urban landscape, wearable technology, and portable power sources is also explored, highlighting the versatile applications of organic solar cells in meeting the diverse energy needs of the modern world. In conclusion, this paper not only provides a thorough historical overview and current state analysis of organic photovoltaics but also forecasts the exciting advancements on the horizon. By identifying the critical factors for the success of organic photovoltaics and proposing strategic directions for future research, this study contributes valuable insights into the ongoing quest for renewable energy solutions. It calls for increased investment and research focus on organic photovoltaics as a key player in the global transition towards a sustainable and energy-efficient future.

Downloads

Download data is not yet available.

References

Bian, L., Zhu, E., Tang, J., Tang, W., & Zhang, F. (2012). Recent progress in the design of narrow bandgap conjugated polymers for high-efficiency organic solar cells. Progress in Polymer Science, 37(9), 1292–1331. https://doi.org/https://doi.org/10.1016/j.progpolymsci.2012.03.001

Blouin, N., Michaud, A., & Leclerc, M. (2007). A low-bandgap poly(2,7-carbazole) derivative for use in high-performance solar cells. Advanced Materials, 19(17), 2295–2300. https://doi.org/10.1002/adma.200602496

Bulavko, G. V., Davidenko, N. A., Derevyanko, N. A., Ishchenko, A. A., & Kulinich, A. V. (2015). Effect of the structure of polymethine dyes on their photovoltaic properties in polymer films. Theoretical and Experimental Chemistry, 51(1), 37–44. https://doi.org/10.1007/s11237-015-9395-9

Bulavko, G. V., Davidenko, N. A., Shkavro, A. G., Tretyak, O. V., Ishchenko, A. A., & Kulinich, A. V. (2017). Photovoltaic effect in dye-doped polymer films with free-surface and sandwich structures. Functional Materials Letters, 10(02), 1750007. https://doi.org/10.1142/S1793604717500072

Camaioni, N., Carbonera, C., Ciammaruchi, L., Corso, G., Mwaura, J., Po, R., & Tinti, F. (2023). Polymer solar cells with active layer thickness compatible with scalable fabrication processes: A meta-analysis. Advanced Materials, 35(8), 2210146. https://doi.org/https://doi.org/10.1002/adma.202210146

Harima, Y., Yamashita, K., & Suzuki, H. (1984). Spectral sensitization in an organic p‐n junction photovoltaic cell. Applied Physics Letters, 45(10), 1144–1145. https://doi.org/10.1063/1.95016

Heeger, A. J. (2014). 25th Anniversary article: Bulk heterojunction solar cells: Understanding the mechanism of operation. Advanced Materials, 26(1), 10–28. https://doi.org/https://doi.org/10.1002/adma.201304373

Hoppe, H., & Sariciftci, N. S. (2004). Organic solar cells: An overview. Journal of Materials Research, 19(7), 1924–1945. https://doi.org/10.1557/JMR.2004.0252

Ishchenko, A. A. (2008). Photonics and molecular design of dye-doped polymers for modern light-sensitive materials. Pure and Applied Chemistry, 80(7), 1525–1538. https://doi.org/10.1351/pac200880071525

Kaienburg, P., Bristow, H., Jungbluth, A., Habib, I., McCulloch, I., Beljonne, D., & Riede, M. (2023). Vacuum-deposited donors for low-voltage-loss nonfullerene organic solar cells. ACS Applied Materials & Interfaces, 15(26), 31684–31691. https://doi.org/10.1021/acsami.3c04282

Kalowekamo, J., & Baker, E. (2009). Estimating the manufacturing cost of purely organic solar cells. Solar Energy, 83(8), 1224–1231. https://doi.org/https://doi.org/10.1016/j.solener.2009.02.003

Koul, S., & Hakim, N. (2018). Recent advances in the determination of optimal active layer thickness for bulk heterojunction organic solar cells. Transactions on Electrical and Electronic Materials, 19(5), 319–329. https://doi.org/10.1007/s42341-018-0053-5

Kurdiukova, I. V., Kulinich, A. V., & Ishchenko, A. A. (2012). Near-infrared squarate and croconate dianions derived from tetranitrofluorene. New Journal of Chemistry, 36(8), 1564. https://doi.org/10.1039/c2nj40303j

Lizin, S., Van Passel, S., De Schepper, E., Maes, W., Lutsen, L., Manca, J., & Vanderzande, D. (2013). Life cycle analyses of organic photovoltaics: a review. Energy & Environmental Science, 6(11), 3136–3149. https://doi.org/10.1039/C3EE42653J

Machín, A., & Márquez, F. (2024). Advancements in photovoltaic cell materials: silicon, organic, and perovskite solar cells. Materials, 17(5), 1165. https://doi.org/10.3390/ma17051165

Panagoda, L. P. S. S., Sandeepa, R. A. H. T., Perera, W. A. V. T., Sandunika, D. M. I., Siriwardhana, S. M. G. T., Alwis, M. K. S. D., & Dilka, S. H. S. (2023). Advancements in photovoltaic (Pv) technology for solar energy generation. Journal of Research Technology & Engineering, 4(3), 30–72. Retrieved from https://www.jrte.org/wp-content/uploads/2023/07/Advancements-In-Photovoltaic-Pv-Technology-for-Solar-Energy-Generation.pdf

Park, S. H., Roy, A., Beaupré, S., Cho, S., Coates, N., Moon, J. S., Moses, D., Leclerc, M., Lee, K., & Heeger, A. J. (2009). Bulk heterojunction solar cells with internal quantum efficiency approaching 100%. Nature Photonics, 3(5), 297–302. https://doi.org/10.1038/nphoton.2009.69

Rehman, F., Syed, I. H., Khanam, S., Ijaz, S., Mehmood, H., Zubair, M., Massoud, Y., & Mehmood, M. Q. (2023). Fourth-generation solar cells: a review. Energy Advances, 2(9), 1239–1262. https://doi.org/10.1039/D3YA00179B

Sariciftci, N. S., Smilowitz, L., Heeger, A. J., & Wudl, F. (1992). Photoinduced electron transfer from a conducting polymer to buckminsterfullerene. Science, 258(5087), 1474–1476. https://doi.org/10.1126/science.258.5087.1474

Scarpulla, M. A., McCandless, B., Phillips, A. B., Yan, Y., Heben, M. J., Wolden, C., ... Hayes, S. M. (2023). CdTe-based thin film photovoltaics: Recent advances, current challenges and future prospects. Solar Energy Materials and Solar Cells, 255, 112289. https://doi.org/10.1016/j.solmat.2023.112289

Shah, N., Shah, A. A., Leung, P. K., Khan, S., Sun, K., Zhu, X., & Liao, Q. (2023). A review of third generation solar cells. Processes, 11(6), 1852. https://doi.org/10.3390/pr11061852

Solak, E. K., & Irmak, E. (2023). Advances in organic photovoltaic cells: A comprehensive review of materials, technologies, and performance. RSC Advances, 13(18), 12244–12269. https://doi.org/10.1039/D3RA01454A

Sonar, P., Fong Lim, J. P., & Chan, K. L. (2011). Organic non-fullerene acceptors for organic photovoltaics. Energy & Environmental Science, 4(5), 1558. https://doi.org/10.1039/c0ee00668h

Spanggaard, H., & Krebs, F. C. (2004). A brief history of the development of organic and polymeric photovoltaics. Solar Energy Materials and Solar Cells, 83(2), 125–146. https://doi.org/https://doi.org/10.1016/j.solmat.2004.02.021

Tang, C. W. (1986). Two‐layer organic photovoltaic cell. Applied Physics Letters, 48(2), 183–185. https://doi.org/10.1063/1.96937


Abstract views: 2363
PDF Downloads: 1079
Published
2024-06-30
How to Cite
Bulavko, G. (2024). Organic photovoltaics: A journey through time, advancements, and future opportunities. History of Science and Technology, 14(1), 10-32. https://doi.org/10.32703/2415-7422-2024-14-1-10-32