The Fe-C diagram – History of its evolution
Abstract
The evolution of concepts and methods of physical and chemical science that contributed to the formation of the Fe-C diagram during the previous centuries is considered. Despite the classical knowledge, there are still differences in the representation of the Fe-C diagram by scientists from different countries, in particular, the data of scientists from Germany, Poland, Ukraine, the USA, and Australia are somewhat mismatched. The authors tried to understand the reasons for this discrepancy. To conduct the research, general scientific methods of cognition were used: comparative analysis and synthesis, as well as a chronological one. It is claimed that the first studies of carbon content in steel were carried out in 1802. Further research development began in 1827–1829 when it was established that graphite is pure carbon. It is emphasized that further studies of carbon content in steel and cast iron are connected with attempts to create the first graphs of dependence on content and temperature. This, in turn, contributed to the development of the industrial revolution. It is believed that the first complete diagram was presented in 1897 by Roberts-Austen. Later, with the use of X-ray methods and microscopy, the Fe-C diagram gradually took on a new form. At the beginning of the 20th century, scientists actively proposed their phase diagrams. Studies conducted by scientists of different countries during 1909–1911 gained a consolidation, which was produced at the 6th Congress of the International Association for testing materials meeting into the unification of the names of phase transformations. Further research until the beginning of the Second World War was aimed at the creation of “pure” steel, that is, without harmful impurities, and clarifying the transformation temperatures. The period of the Great Depression in the USA and the war in Europe did not contribute to scientific research. At the same time, for the mass production of steel and cast iron, errors in critical points of a few degrees did not have a significant impact, that is, refining the temperatures of phase transformations were not considered appropriate. Today’s trend in scientific research is aimed at solving environmental problems caused by the industrial revolution.
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References
Austin, J. B. (1948). C-Fe Carbon-Iron. In T. Lyman (Ed.), Metals Handbook (pp. 1181–1182). Cleveland: American Society for metals.
Authier, A. (2013). Early Days of X-ray Crystallography. Oxford: Oxford University Press. https://doi.org/10.1093/acprof:oso/9780199659845.001.0001
Berzelius, J. J. (1841). Jahresbericht über die Fortschritte der Physischen Wissenschaften, 20. Tübingen: Heinrich Laupp. Retrieved from https://www.digitale-sammlungen.de/de/view/bsb10130758?q=%28Jahresbericht+%C3%BCber+die+Fortschritte+der+physischen+Wissenschaften+1841%29&page=30,31 [in German].
Bhadeshia, H. K. D. H., & Honeycombe, R. (2006). Iron and its interstitial solid solutions. In Steels: Microstructure and Properties (3rd ed.) (pp. 1–16). Oxford: Butterworth-Heinemann. http://dx.doi.org/10.1016/B978-075068084-4/50003-0
Bobrova, T. B. (2016). Osnovy materialoznavstva. Navchalnyi posibnyk ‒ [Basics of materials science. Tutorial]. Kyiv: GURT Resource Center. Retrieved from https://www.gurt.org.ua/uploads/news/files/2016-8/Матеріалознавство-min.pdf [in Ukrainian].
Chicco, B., & Thorpe, W. R. (1982). Experimental determination of the austenite + liquid phase boundaries of the Fe-C system. Metallurgical and Materials Transactions A, 13, 1293–1297. https://doi.org/10.1007/BF02645513
Chicco, B., & Thorpe, W. R. (1983). A further determination of the austenite solidus of the Fe-C system. Metallurgical and Materials Transactions A, 14, 312–314. https://doi.org/10.1007/BF02651629
Cleaves, H. E., & Hiegel, J. M. (1942). Properties of high purity iron. Journal of Research of the National Bureau of Standards, 28(5), 643–669. http://dx.doi.org/10.6028/jres.028.027
Debye, P., & Scherrer, P. (1916). Interferenzen an regellos orientierten Teilchen im Röntgenlicht. I. In Nachrichten von der Gesellschaft der Wissenschaften zu Göttingen, Mathematisch-Physikalische Klasse, 1916 (pp. 1–15). Berlin: Weidmanndsche Buchhandlung. Retrieved from https://gdz.sub.uni-goettingen.de/id/PPN252457811_1916?tify=%7B%22view%22:%22info%22,%22pages%22:%5B5%5D%7D [in German].
Eckstein, H.-J. (1969). Wärmebehandlung von Stahl: Metallkundliche Grundlagen. Leipzig: Deutscher Verlag für Grundstoffindustrie VEB [in German].
Fedirko, P. Krol, V., Hutsol, T., … & Dziedzic, B. (2017). Materialoznavstvo i sliusarna sprava ‒ [Materials science and metalworking]. Krakow, Kamianets-Podilskyi: Traicon. Retrieved from https://depot.ceon.pl/bitstream/handle/123456789/13411/MATERIALS%20SCIENCE%20AND%20METALWORKING.pdf?sequence=1&isAllowed=y [in Ukrainian].
Finanzierung des SALCOS®-Programms gesichert (2023). Stahl und Technik, (3), 30‒31. Retrieved from https://www.stahl-und-technik.de/artikel/finanzierung-des-salzgitter-salcos-programms-gesichert [in German].
Geiger, C. (1925). Die Begriffe “Eisen” und “Stahl”. In C. Geiger, (Ed.), Handbuch der Eisen- und Stahlgießerei. (pp. 1‒7). Berlin, Heidelberg: Springer. https://doi.org/10.1007/978-3-642-90865-1_1 [in German].
Gutnyk, M. (2012). Robert Forester Miushet – liudyna, yaka nadala formu suchasnomu svitu [Robert Forester Mushet – the man who gave a shape to the modern world]. Materialy 11-yi Vseukrainskoi naukovoi konferentsii «Aktualni pytannia istorii nauky i tekhniky» [Materials of the 11th All-Ukrainian Scientific Conference “Current Issues in the History of Science and Technology”], Kyiv, October 4-6, 2012, (pp. 253–255). Kyiv: Center for Monument Studies of the National Academy of Sciences of Ukraine and UTOPIK [in Ukrainian].
Hartbrich, I. (2023, June 19). Thyssenkrupp und Zweiter Kohleausstieg an der Ruhr. VDI Nachrichten. Retrieved from https://www.vdi-nachrichten.com/technik/werkstoffe/thyssenkrupp-und-der-zweite-kohleausstieg-an-der-ruhr/ [in German].
Heyn, E. (1912). Report on the progress of metallography since the commencement of the year 1909 to the end of the year 1911. In Sixth congress of the International Association for Testing Materials, held in New York, September 3‒7, 1912, Vol. 1, Part II(1). New York: McGraw-Hill. Retrieved from https://babel.hathitrust.org/cgi/pt?id=coo.31924004059048&seq=105
Horstmann, D. (1985). Das Zustandsschaubild Eisen-Kohlenstiff und die Grundlagen derv Wärmebehandlung der Eisen-Kohlenstoff-Legierungen. Düsseldorf: Verlag Stahleisen [in German].
Howe, H. M., & Sauveur, A. (1912) The Nomenclature of the Microscopic Substances and Structures of Steel. In Sixth congress of the International Association for Testing Materials, held in New York, September 3‒7, 1912, Vol. 1, Part II(7). New York: McGraw-Hill. Retrieved from https://babel.hathitrust.org/cgi/pt?id=coo.31924004059048&seq=246
Hucińska, J. (1995). Мetaloznawstwo materiały do ćwiczeńlaboratoryjnych. Gdansk: Wydawnictwo Politechniki Gdańskiej. Retrieved from https://pbc.gda.pl/dlibra/publication/edition/4096/content [in Polish].
Industrienormen Deutsche (1922). Werkstoffnormen für Eisen und Stahl, herausgegeben vom Normenausschuß der Deutschen Industrie. Berlin: Selbstverlag des Normenausschusses [in German].
Ito, A., Langefeld, B., & Götz, N. (2020). The Future of Steel making ‒ How the European Steel Industry Can Achieve Carbon Neutrality. Munich: Roland Berger GMBH. Retrieved from https://www.rolandberger.com/publications/publication_pdf/rroland_berger_future_of_steelmaking.pdf
Karsten, C. J. B. (1816). Handbuch der Eisenhüttenkunde. Vol. 1: Die Eigenschaften des Eisens. Halle: Curt. Retrieved from https://www.digitale-sammlungen.de/de/view/bsb10706033?page=,1 [in German].
Kayser, F. X., & Patterson, J. W. (1998). Sir William Chandler Roberts-Austen – His role in the development of binary diagrams and modern physical metallurgy. Journal of Phase Equilibria, 19, 11‒18. https://doi.org/10.1007/BF02904718
Kleier, T., & Hansmann, Th. (2023). Maßgeschneiderte Dekarbonisierung. Stahl und Eisen, 06, 16–17 [in German].
Kueppers, M., Hodgson, D., Levi, P., Vass, T., & Lechtenbohmer, T. (2022). Iron and Steel. International Energy Agency. Retrieved from https://www.iea.org/reports/iron-and-steel
Läpple, V. (2022). Wärmebehandlung des Stahls. Haan-Gruiten: Europa-Lehrmittel [in German].
Ledebur, A. (1888). Über die Benennung der verschiedenen Kohlenstofform en im Eisen. Stahleisen, 742 [in German].
Ledebur, A. (1906). Handbuch der Eisenhüttenkunde, Vol. 1: Für den Gebrauch im Betriebe wie zur Benutzung Beim Unterrichte Bearbeitet; Einführung in die Eisenhüttenkunde (Classic Reprint). Leipzig: Arthur Felix [in German].
Lee, D. N., & Han, H. N. (2012). Directed growth of ferrite in austenite and Kurdjumov-Sachs orientation relationship. Materials Science Forum, 715–716, 128–133. https://doi.org/10.4028/www.scientific.net/MSF.715-716.128
Leitprojekt Dekarbonisierung. (2023). Stahl und Eisen, 03, 16–17 [in German].
Ma, Y., Bae, J. W., Kim, S.-H., Jovičević-Klug, M., Li, K., Vogel, D., … & Raabe, D. (2023). Reducing iron oxide with ammonia: A sustainable path to green steel. Advanced Science, 10, 2300111. https://doi.org/10.1002/advs.202300111
Mourelo, J. R. (1916). L’oeuvre de Proust en Espagne. Revue scientifique, 54, 257–266 [in French].
Mushet, D. (1802). XXIV. On the different proportions of carbon which constitute the various qualities of Crude iron and steel. Philosophical Magazine, 13(50), 142–149. https://doi.org/10.1080/14786440208676104
Nürnberger, F., Frolov, I., Grydin, O., Gutnyk, M., & Blank, T. (2022). Materials Testing. Hannover. https://doi.org/10.57961/5fbf-7745
Osmond, F. (1886). Sur les phénomènes qui se produisent pendant le chauffage et le refroidissement de l’acier fondu. Comptes rendus,103, 743–746; 1135–1137 [in French].
Osmond, F., & Cartaud, G. (1906). Die Kristallographie des Eisens. Metallurgie, 3, 522 [in German].
Ostwald, W. (1974). J. B. Richter. In Günther Bugge: Das Buch der grossen Chemiker, Vol. 1 (p. 375). New York, Weinheim: Verlag Chemie [in German].
Pawłowski, B. (2012). Temperatura przemiany magnetycznej cementytu, XL Szkoła Inżynierii Materiałowej, 24–27 IX 2012 (pp. 1–5). Kraków: Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Retrieved from https://www.researchgate.net/profile/Bogdan-Pawlowski/publication/251880650_Temperatura_przemiany_magnetycznej_cementytu/links/0c96051f247cc3500e000000/Temperatura-przemiany-magnetycznej-cementytu.pdf [in Polish].
Pawłowski, B. (2017). 8. Obróbka cieplna i cieplno-chemiczna stali. In Wydzial Chemiczny Technologia Chemiczna (pp. 144–167). Retrieved from https://www.studocu.com/pl/document/politechnika-slaska-w-gliwicach/wydzial-chemiczny-technologia-chemiczna/dr-inz-bogdan-pawlowski-obrobka-cieplna-i-cieplno-chemiczna-stali/31346752 [in Polish].
Pfender, M. (1990). Martens Adolf. In Neue Deutsche Biographie (NDB), 16, (pp. 266–273). Berlin: Band Duncker & Humblot. Retrieved from https://www.deutsche-biographie.de/pnd116800453.html#ndbcontentCC-BY-NC-SA [in German].
Roberts-Austen, W. C. (1897). Fourth report to the alloys research committee. Proceedings of the Institution of Mechanical Engineers, 52(1), 31‒100. https://doi.org/10.1243/PIME_PROC_1897_052_009_02
Rocke, A. J. (2005). In search of El Dorado: John Dalton and the origins of the atomic theory. Social Research: An International Quarterly, 72(1), 125–158. https://doi.org/10.1353/sor.2005.0003
Roeser, Wm. F., & Wensel, H. T. (1941). Freezing temperatures of high purity iron and some steels. Journal of Research of the National Bureau of Standards, 26(4), 273–287. https://doi.org/10.6028/jres.026.015
Roozeboom, H. W. B. (1900). The Metallographist, 3, 293–300.
Ruer, R., & Klesper, R. (1914). Die γ-δ-Umwandlung des reinen Eisens und ihre Beeinflussung durch Kohlenstoff, Silizium, Kobalt und Kupfer. Ferrum, 11, 257‒261 [in German].
Sefström, N. G. (1828). Berättelser rörande göromalen vid Bergsskolan ar 1827. Jern-Kontorets Annaler, 12, 145 [in German].
Sefström, N. G. (1829). Versuche zur Ausmittlung der Natur des Graphits. Annalen der Physik, 16, 168 [in German].
Seljakow, N., Kurdjumow, G., & Goodtzow, N. (1927). Eine röntgenografische Untersuchung der Struktur des Kohlenstoffstahls. Zeitschrift für Physik, 45, 384–408. https://doi.org/10.1007/BF01343061 [in German].
Shakhnazarov, K., & Pryakhin, E. (2016). Plasticity anomaly of iron as a result of transformation at ~650°C. Journal of Mining Institute, 217, 150–154. Retrieved from https://pmi.spmi.ru/pmi/article/view/5093/2958 [in Russian].
The engineering and mining journal. (1912, September 14). The engineering and mining journal, 94(11), 484.
Timofeeva, L., & Komarova, G. (2013). Materialoznavstvo ta tekhnolohiia konstruktsiinykh materialiv. Chastyna 1 [Materials science and technology of structural materials: Lecture notes. Part 1]. Kharkiv: UkrDAZT. Retrieved from http://lib.kart.edu.ua/handle/123456789/6702 [in Ukrainian].
Tyrkiel, E. (1963). Wykres zelazo-węgiel w rozwoju historycznym. Wroclaw-Warszawa-Krakow: Wydawnictwo Polskiej Akademii Nauk [in Polish].
Vercammen, S. (2022, August 1). Steel. Transition to net zero, McKinsey Quarterly. Retrieved from https://www.mckinsey.com/capabilities/sustainability/our-insights/spotting-green-business-opportunities-in-a-surging-net-zero-world/transition-to-net-zero/steel
Wadsworth, J., & Sherby, O. D. (1997). The History of ultrahigh carbon steels. The Metallurgical Society 1997 Materials week, Indianapolis, IN (United States), September 14–17, 1997, (pp. 1‒42). Retrieved from https://www.osti.gov/servlets/purl/611842
Wessel, H. A. (2009). Globale Unternehmensaktivitäten im Spannungsfeld von unternehmerischem Gestaltungswillen und (wirtschafts-) politischen Realitäten. Das Beispiel der Familie Mannesmann aus Remscheid. In Hilger, Susanne/Soénius, Ulrich S. (Hg.), Familienunternehmen im Rheinland im 19. und 20. Jahrhundert, (pp. 66–102). Köln: Stiftung Rheinisch-Westfälisches Wirtschaftsarchiv [in German].
Westgren, A., & Lindh, A. E. (1921). Zum Kristallbau des Eisens und Stahl. Zeitschrift fuer Physikalische Chemie, 98(1), 181‒210. https://doi.org/10.1515/zpch-1921-9815 [in German].
Westgren, A., & Phragmen, G. (1922). X-rays studies on the crystal structure of steel. Journal of the Iron and Steel Institute, 105, 241–273.
Wisniak, J. (2003). Hendrik-Willem Bakhuis Roozeboom: Equilibrium and Phase Topology. Journal of Phase Equilibria, 24, 422–430. https://doi.org/10.1361/105497103770330073
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